Rolling bearing and its packaging method

ABSTRACT

To provide a rolling bearing in which a favorable antirust performance can be obtained while reducing an amount of antirust oil than before, after removing chloride ions and sulfate ions from the entire surface of the bearing, antirust oil is provided to adhere thereto at an average film thickness of 4.5 μm to 10 μm, and the entire bearing is covered with a volatile corrosion inhibitor film such that a space between the volatile corrosion inhibitor film and the bearing is kept in a pressure-reduced condition.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No.14/655,403 filed Jun. 25, 2015, which is U.S. National Stage ofInternational Application no. PCT/JP2013/076967 filed Oct. 3, 2013,which claims priority to Japanese Application No. 2013-115810 filed May31, 2013. The entire disclosures of the prior applications areconsidered part of the disclosure of the accompanying continuation, andare hereby incorporated by reference.

TECHNICAL FIELD

The present invention relates a rolling bearing and its packagingmethod.

BACKGROUND ART

In recent years, for machine tool bearings (in particular, machine toolspindle bearings), minimal quantity lubrication methods such as oillubrication, e.g., oil-air or oil-mist lubrication, and greaselubrication are used to reduce a temperature rise due to stirringresistance of lubricating oil. In oil lubrication, measures should betaken in view of a cost increase due to use of air, environmentalconsiderations with regard to wind noise due to rolling elements cuttingthe air injected from a nozzle into a bearing interior and passingthrough the bearing interior, and outflow of used oil through an oildischarging hole, and also working environment considerations withregard to impact on human bodies, deterioration of visibility and thelike due to floating of oil mists.

In light of such backgrounds, such as energy saving and reduction ofenvironmental impact, for machine tool spindle bearings, there areincreasing needs for a grease lubrication method in which there is nousage of air or outflow of lubricating oil.

Bearings are generally packaged during storage or transport, and areunpacked and charged with grease immediately before use. To preventrusting during storage or transport, the bearings are packaged in astate in which antirust oil is applied to the entire surface of thebearing. Accordingly, if the bearing is charged with grease directlyafter the unpacking, the grease does not firmly adhere to a surface tobe lubricated due to the antirust oil, and the grease may leak out at anearly stage during an initial running-in period or in a subsequentoperation, resulting in a grease life being reduced.

In particular in the case of machine tools, the maximum dmn value of abearing during its operation is high, at least 500,000, and lowtemperature rise characteristics are required. Accordingly, to preventstirring resistance due to excessive lubricant, a grease charge amountis reduced as compared with bearings used in general applications, suchas motor bearings. A charging amount of grease in a bearing for amachine tool is 10 vol % to 20 vol %, sometimes 10 vol % to 15 vol % ofa bearing interior space. Therefore, if a bearing for a machine tool ischarged with grease directly after the unpacking as described above, thegrease leaks out and the amount of residual grease becomes extremelysmall.

In addition, in grease lubrication, lubricating oil inside the bearingis not exchanged during use. Accordingly, if foreign substances enterthe bearing interior during packaging, the foreign substances remain andhinder a rotation.

Therefore, after the unpacking and before charging with grease, it isnecessary to clean and degrease bearings to remove the adhered antirustoil and foreign substances inside the bearings, causing a burden whenmounting the bearings. Thus, the applicant proposes, in Patent Document1, applying antirust oil on a surface of a bearing at a film thicknessof 40 μm or less, packaging the entire bearing with a volatile corrosioninhibitor film, and keeping a pressure-reduced condition between thevolatile corrosion inhibitor film and the bearing. Because an adheredamount of the antirust oil is 40 μm or less, effects on grease can besuppressed even if the grease is provided without undergoing cleaningand degreasing after the unpacking. Also, due to an airtight packagingby the volatile corrosion inhibitor film, a sufficient antirust effectcan be obtained even if the adhered amount of antirust oil is reduced to40 μm or less.

PRIOR ART DOCUMENT Patent Document

Patent Document 1: JP 2006-322604 A

SUMMARY OF INVENTION Problem to be Solved by Invention

However, there are strong demands for further reducing effects on greaseby reducing the adhered amount of antirust oil, and accordingly, it isan object of the present invention to provide a rolling bearing in whicha favorable antirust performance can be obtained while further reducingthe amount of antirust oil than before.

Means for Solving the Problem

To solve the above object, the present invention provides a rollingbearing and its packaging method described below.

(1) A rolling bearing including an inner ring, an outer ring, and aplurality of rolling elements retained between the inner ring and theouter ring by a retainer in a rollable manner, wherein antirust oil isprovided to adhere, at an average film thickness of 4.5 μm to 10 μm, toan entire surface of the bearing from which chloride ions and sulfateions are removed, the entire bearing is covered with a volatilecorrosion inhibitor film, and a space between the volatile corrosioninhibitor film and the bearing is kept in a pressure-reduced condition.(2) The rolling bearing according to (1), wherein an amount of residualchloride ions adhered to the rolling bearing per unit area is 0.2 ng/mm²10 ng/mm².(3) The rolling bearing according to (1) or (2), wherein the entirebearing is covered with the volatile corrosion inhibitor film and thespace between the volatile corrosion inhibitor film and the bearing iskept in the pressure-reduced condition, in a state in which a bearinginterior space defined by the inner ring, the outer ring and the rollingelements is charged with grease.(4) A method of packaging a rolling bearing after assembling the rollingbearing from bearing components, the method including after removingchloride ions and sulfate ions from the entire surface of the bearing,providing antirust oil to adhere thereto at an average film thickness of4.5 μm to 10 μm, and covering the entire bearing with a volatilecorrosion inhibitor film such that a space between the volatilecorrosion inhibitor film and the bearing is kept in a pressure-reducedcondition.(5) The method of packaging the rolling bearing according to (4),wherein the chloride ions and the sulfate ions are removed from theentire surface of the rolling bearing such that an amount of residualchloride ions adhered to the rolling bearing per unit area is 0.2 ng/mm²to 10 ng/mm².(6) The method of packaging the rolling bearing according to (4) or (5),wherein after the adhesion of the antirust oil, a bearing interior spacedefined by an inner ring, an outer ring and rolling elements is chargedwith grease, and the entire bearing is covered with the volatilecorrosion inhibitor film such that the space between the volatilecorrosion inhibitor film and the bearing is kept in the pressure-reducedcondition.

Advantageous Effects of Invention

According to the present invention, because the antirust oil is providedto adhere after removing chloride ions and sulfate ions and then sealedand packaged by a volatile corrosion inhibitor film, a favorableantirust performance can be obtained while reducing an adhered amount ofantirust oil than before. Therefore, even if grease is provided withoutcleaning or degreasing after unpacking, effect by the antirust oil isfurther reduced, so that lubrication performance and lifetime areimproved.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a graph showing a relationship between storage conditions ofbearings and amounts of residual chloride ions on surfaces of thebearings.

FIG. 2 is a perspective view showing an angular ball bearing as anexample of a rolling bearing according to the present invention.

FIG. 3 is a perspective view showing a single-row cylindrical rollerbearing as another example of a rolling bearing according to theinvention.

FIG. 4 is a perspective view showing a single-row cylindrical rollerbearing as yet another example of a roller bearing according to theinvention, illustrating a state in which an inner ring assembly,including an inner ring, rolling elements and a retainer assembledtogether, and an outer ring are separately packaged.

FIG. 5 is a perspective view showing a double-row cylindrical rollerbearing as yet another example of a rolling bearing according to theinvention.

FIG. 6 is a perspective view showing a double-row cylindrical rollerbearing as yet another example of a rolling bearing according to theinvention, illustrating a state in which an inner ring assembly,including an inner ring, rolling elements and a retainer assembledtogether, and an outer ring are separately packaged.

FIG. 7 is a graph showing results of Test Example 1.

FIG. 8 is a diagram illustrating a test apparatus used in Test Example 2and Test Example 4.

FIG. 9 is a graph showing results of Test example 2.

FIG. 10 is a graph showing results of Test example 3.

FIG. 11 is a graph showing results of Test example 4.

EMBODIMENTS OF INVENTION

Hereinafter, the present invention will be described in detail withreference to the drawings.

According to a rolling bearing of the present invention, afterassembling, and after removing chloride ions and sulfate ions from theentire surface of the bearing, antirust oil provided to adhered theretoand is sealed by a volatile corrosion inhibitor film. By removing therust-inducing chloride ions and the sulfate ions, a favorable antirustperformance can be ensured even with an adhered amount of antirust oilbeing reduced to an average film thickness of 4.5 μm to 10 μm, so thateffect of the antirust oil on grease can be eliminated even if thegrease is provided without cleaning or degreasing after unpacking.

Chloride ions and sulfate ions are adhered to the bearing surface fromvarious machines or chemicals and workers during manufacturing processesof the bearing. To remove chloride ions and sulfate ions, for example,it may be cleaned with a water substitution type cleaning liquid. Bythis cleaning, it is preferable that an amount of the residual chlorideions on the surface of the rolling bearing be 0.2 ng/mm² to 10 ng/mm².

Grinding is mostly used in the manufacturing processes of the rollingbearing, but grinding is generally performed while applying a largeamount of grinding water to prevent dimensional changes of products dueto heat accompanied with such processing. A tap water is used as thegrinding water, and the tap water inevitably contains chlorinecomponents, namely chloride ions.

Under the Waterworks Law, an amount of chloride ions in the tap water isregulated to be kept to 0.1 mg/L or more, and also defined is a waterquality management target value by which the upper threshold is limitedto 1 mg/L or less in view of taste or smell. Therefore, in themanufacturing of the rolling bearing, the grinding water will alsocontain chloride ions of 0.1 mg/L to 1 mg/L. During grinding, a largeamount of grinding water of approximately several tens liters is appliedto the rolling bearing, and thus a significant amount of chloride ionsare adhered on the rolling bearing.

In addition, a large amount of chloride ions is contained in human bodyfluids (such as sweat or saliva), and thus chloride ions are remained inlocations where hands are touched. Further, chloride ions are alsocontained in the atmosphere, and thus, chloride ions in the atmosphereare adhered on the rolling bearing exposed to the atmosphere. Even ifthe rolling bearing is contained in a sealed container to preventexposing to the atmosphere, adhesion of a trace amount of chloride ionsthereon is inevitable.

In FIG. 1, a relationship between storage conditions (outdoor storage inthe atmosphere, indoor storage in the atmosphere, and indoor storage inan air-tight container) of bearings and amounts of residual chlorideions on surfaces of the bearings is shown. The measurement of amounts ofresidual chloride ions was performed according to the followingprocedures (rubber gloves are used in each step) and also was performedusing a chlorine ion detector tube 201SA produced by Komyo RikagakuKogyo K.K.

(Measurement Method)

(1) Masking portions other than a measurement portion (such as a bearingouter peripheral surface) on a bearing by a masking tape after beingstored in the atmosphere or in a sealed container for a predeterminedperiod of time.

(2) Providing deionized water of 100 mL in a poly beaker.

(3) Folding a gauze suitably and soaking it in the deionized water inthe beaker.

(4) Wiping the measurement portion with the wetted gauze in paralleldirections.

(5) Thoroughly rinsing the gauze is thoroughly with the deionized waterin the beaker.

(6) Repeating (4) and (5).

(7) After collecting, thoroughly cleaning a surface of the used rubbergloves with a deionized water of 50 mL, and returning the deionizedwater used for the cleaning back in the beaker to use as a sampleliquid.

(8) Cutting both ends of a chlorine ion detector tube by a tip cutterand placing the chlorine ion detector tube in the sample liquid with anarrow oriented upward.

(9) If salt exists in the sample liquid, a white discoloration layerappears from the lower end of the detector tube. When the sample liquidis permeated to the upper end of the detector tube, the detector tube istaken out and then chloride content in the sample liquid is read by ascale at a distal end of the discoloration layer.

As shown in FIG. 1, it can be found that, even if rolling bearings arestored in the atmosphere or in the sealed container, chlorides have beenadhered thereon. The amount of residual chloride ions adhered to thebearing per unit area is calculated by the following equation, where Vis an amount of residual chloride ions adhered to the bearing per unitarea, T is an adhered amount of chloride ions, and S is a surface areaof a measurement portion of the bearing used upon measuring of an amountof chloride ions.V=T/S

Because the adhered chloride ions effect rusting of the rolling bearing,according to the present invention, the amount of chloride ions per unitarea is limited to 0.2 ng/mm² to 10 ng/mm².

The antirust oil is not particularly limited if the antirust oil is onein which stickiness is hardly occurred so that workability is excellentand also an adhered amount thereof can be easily controlled, but, forexample, antirust oil, which does not contain petrolatum, is preferablyemployed. In addition, to easily control an adhering amount of theantirust oil, viscosity of the antirust oil is preferably in a range of10 cst to 60 cst.

Further, a method of adhering the antirust oil is not particularlylimited if a film thickness thereof can be adjusted, but, for example,can include a centrifugal deoiling method, an air blowing method, or avacuum heating method. In particular, to evenly adhere the antirust oil,the air blowing method is preferably employed.

An adhered amount of antirust oil is set to an average film thickness of4.5 μm to 10 μm. If the average film thickness is less than 4.5 μm, itis difficult to keep antirust performance for a long time. In addition,because the antirust oil is reacted with grease to cause precipitationof crystals and thus to reduce an acoustic property, the reactionthereof with grease is likely to be occurred if the adhered amount ofantirust oil exceeds an average film thickness of 10 μm.

The volatile corrosion inhibitor film may be a resin film, such aspolyethylene film, containing an antirust agent, such as organiccarboxylic acid amine salts, phosphoric acid amine salts, aminecarbonate salts, heterocyclic amine salts, or the like. More specificexamples of the antirust agents can include dicyclohexyl ammoniumnitrite, dicyclohexyl ammonium caprylate, cyclohexylamine carbamate,cyclohexylamine laurate, diisopropyl ammonium nitrite, nitronaphthaleneammonium nitrite, ammonium benzoate, cyclohexylamine benzoate salts,dicyclohexylamine phosphate salts, and the like. To envelop the rollingbearing and to keep a pressure-reduced condition, the volatile corrosioninhibitor film in a form of a bag, as shown in FIGS. 1 to 5, ispreferably used.

In addition, the volatile corrosion inhibitor film is preferablytransparent, and by making the volatile corrosion inhibitor filmtransparent, stamping or the like can be checked in a packaged state.For example, when inspection results, such as dimensional differences,are directly imprinted on the bearing by a laser marker or the like,such inspection results can be checked without polluting the bearing. Inparticular, if being imprinted on an outer ring end surface, an innerring end surface, an outer ring outer-diameter surface or the like, theinspection results can be more easily checked.

Further, the volatile corrosion inhibitor film and the bearing becomes asealed state by reducing a pressure therebetween. Also, to keep such apressure-reduced condition obtained by vacuum drawing, sealing, such asheat sealing, is performed.

By this packaging, rusting of the rolling bearing or adhering of foreignsubstances in the atmosphere thereto during storage or transport can bereliably prevented. In addition, cleaning or degreasing is not required,and also even when grease is provided therein, an effect of the antirustoil thereon is more reduced, thereby keeping a good lubricating ability.

The packaging described above may be performed in a state in whichgrease is provided in a bearing interior space defined by an inner ring,an outer ring and rolling elements, or in a state in which the grease isnot provided. By packaging in a state in which the grease is provided,grease charge before use becomes unnecessary. Because the space betweenthe volatile corrosion inhibitor film and the bearing is in apressure-reduced condition, the packaging film enters a space betweeninner and outer rings in a concave manner to prevent grease from beingflowed out even if it is vibrated during transport.

The present invention is not limited to types of rolling bearings, andfor example, can be applied to packaging of an angular ball bearing 1 asshown in FIG. 2. Namely, the angular ball bearing 1 immediately aftermanufacturing is cleaned with a water substitution type cleaning liquidto remove chloride ions and sulfate ions and then after antirust oil isprovided to adhered thereto at an average film thickness of 4.5 μm to 10μm, is put in a bag made of a volatile corrosion inhibitor film 10, andthe bag is vacuum drawn and sealed by heat sealing or the like. In thedrawings, the reference numeral 11 denotes a sealing portion.

As shown in FIG. 3, the present invention can be applied in a similarmanner in packaging a single-row cylindrical roller bearing 2.

Also, as shown in FIG. 4, an inner ring-side member of the single-rowcylindrical roller bearing 2, which includes an inner ring 2A,cylindrical rollers 2B and a retainer 2C assembled together with eachother, and an outer ring 2D thereof may be put in separate bags made ofa volatile corrosion inhibitor film 10. By separately storing the innerring-side member and the outer ring 2D, a sealed state thereof can bekept until immediately before the bearing is mounted, thereby moreeffectively inhibiting adhering of foreign substances in the atmosphereor rusting. When the inner ring-side member and the outer ring 2D areseparately packaged in this way, packaging is performed in a state inwhich grease is not enclosed therein.

In addition, a double-row cylindrical roller bearing 3 may be packagedas shown in FIG. 5 and also an inner ring-side member of the double-rowcylindrical roller bearing 3, which includes an inner ring 3A,cylindrical rollers 3B and a retainer 3C assembled together with eachother, and an outer ring 3D thereof may be put and sealed in separatebags made of a volatile corrosion inhibitor film 10 as shown in FIG. 6.

EXAMPLES

Now, the present invention will be further described with reference toTest Examples, but the present invention is not limited by this.

Test Example 1 Antirust Performance Test

Angular ball bearings (inner diameter: 40 mm, outer diameter: 68 mm, andwidth: 15 mm) of a bearing number 7008CTYNDBLP4 immediately afterassembly were prepared and was cleaned with a water substitution typecleaning liquid (“Aqua Solvent” produced by Aqua Chemical Co., Ltd.) toremove chloride ions and sulfate ions on a surface thereof. Next,lubricating oil (“ANTIRUST P-2810” produced by JX Nippon Oil & EnergyCorporation; viscosity: 12 cst), which does not include petrolatum, wasadhered as an antirust agent on the entire surface of the bearings by anair blowing method while varying an adhering amount thereof. Then, thebearings were put in bags made of a volatile corrosion inhibitor film(“BOSELON®” produced by Aicello Chemical Co., Ltd.) and the bags weresealed by heat sealing after vacuum drawing, thereby obtaining testsamples. Meanwhile, an average film thickness (t) of the antirust oilwas calculated by the following equation, where ΔS is an adhered amountof antirust oil and S is the entire surface of rolling members (an outerring, an inner ring, a retainer and rolling elements) of the rollingbearing). Also, the adhered amount (ΔS) was obtained by measuring adifference (M) in weight before and after the antirust oil was adheredand dividing the difference by a specific gravity (ρ) of the antirustoil.T=ΔS/S (ΔS=M/ρ)

Then, each test sample was left in a high temperature and high humidityenvironment of 50° C.—90% RH and periods of time until rust was occurredwere compared. In the environment of 50° C.—90% RH, an effect ofaccelerating rusting by approximately 30 times is obtained as comparedwhen samples were left at 20° C.—70% RH, which are the averagetemperature and humidity in Japan, and the equivalent numbers of yearsare shown in the figure. The results are shown in FIG. 7, but it can befound that, when the adhered amount of antirust oil is less than anaverage film thickness of 4.5 μm, antirust performance in a packed stateis significantly decreased. From the results, it can be found that afavorable antirust performance can be kept for a long time by settingthe adhered amount of antirust oil to an average film thickness of 4.5μm or more.

Test Example 2 Grease Holding Ability Test

The test samples fabricated in Test example 1 were opened and then abearing interior space defined by an inner ring, an outer ring and ballswas charged with grease (MTE produced by NSK Ltd.) of 1.1 g (15% of thebearing interior space volume), thereby fabricating test bearings. Then,after rotating the bearings for 24 hours at conditions as describedbelow, using a tester as shown in FIG. 8, grease residual rates weremeasured. Also, for comparison, the same bearings, on which cleaning anddegreasing was performed and antirust oil was not adhered, were chargedwith grease to fabricate comparative test bearings, and grease residualrates were in the same manner. The term grease residual rate means avalue which is obtained by subtracting a percentage, which isrepresented by a value obtained by dividing a difference between abearing weight (M1) in a grease-charged condition before rotating and abearing weight (M2) after rotating by a charged amount of grease (M3),from 100, and if the grease residual rate is low, a grease life isshortened.

-   -   Pre-pressure upon mounting: 120N    -   Number of revolutions: 10000 min⁻¹(dm·n=54×10⁴)    -   Operation position: Vertical    -   Driving method: Belt driving    -   Cooling of an outer cylinder: No

The results are shown in FIG. 9, but it can be found that when theaverage film thickness is up to 10 μm, the test bearings have a greaseresidual rate of 97% on average as compared with the comparative testbearings having a grease residual rate of 99%, and therefore, the testbearings have a grease holding ability equivalent to those in aconventional using method in which grease charge is performed aftercleaning and degreasing bearings. On the other hand, when the averagefilm thickness is 15 μm or more, the grease residual rate tends to bedecreased. From the results, it can be found that a grease holdingability equivalent to those in a conventional case, and thus alubrication lifetime can be kept by setting the adhered amount ofantirust oil to an average film thickness of 10 μm or less.

Test Example 3 Grease Precipitation Test

Test bearings prepared by cleaning deep groove ball bearings of abearing number 6202 with a water substitution type cleaning agent,providing antirust oil to adhere at an average film thickness of 10 μmand then charging with grease (MTE or MTS produced by NSK Ltd., orISOFLEX NBU 15 produced by NOK KLUBER Co., Ltd.), and comparative testbearings prepared by cleaning and degreasing, and charging with thegrease without providing the antirust oil to adhere, were fabricated, 10units for each test bearing, 60 units in total.

Also, after each test bearing was placed in a constant temperature bathand then a heating cycle in which the temperature is changed from “0°C.→30° C.→60° C.” every few hours, was repeated 7 times, a noise countmeasurement was performed one time, and such a measurement was performed4 times in total. Noise counts before and after heating cycles ofbearings were measured using a noise tester mounted in a known anderondevice (acoustic measurement device).

The results are shown in FIG. 10, but no significant difference betweentest bearings and comparative test bearings in initial noise countnumber and noise count number after heating cycles of 4 times wasexhibited. From the results, it can be found that, by setting theadhered amount of antirust oil to an average film thickness of 10 μm orless, precipitation of crystals due to reaction of grease is notoccurred.

Test Example 4 Bearing Temperature Rise Test

Test samples, in which the adhered amount of antirust oil in Testexample 1 were adjusted to an average film thickness of 10 μm, wereopened and then were charged with grease (MTE produced by NSK Ltd.) of1.1 g (15% of the bearing interior space volume), thereby fabricatingtest bearings. Also, for comparison, comparative test bearings, whichwere charged with grease without adhering antirust oil after cleaningand degreasing, were fabricated. Then, each test bearing was rotated atconditions as described below, using the test apparatus used in Testexample 2, and a temperature of the outer ring thereof at that time wasmeasured.

-   -   Pre-pressure upon mounting: 120N    -   Number of revolutions: 12000 min⁻¹(dm·n=65×10⁴)    -   Operation position: Vertical    -   Driving method: Belt drive    -   Cooling of outer cylinder: No

The results are shown in FIG. 11, but no significant difference betweentest bearings, on which the antirust oil was adhered at the average filmthickness of 10 μm, and comparative test bearings in temperature risecharacteristics was exhibited. From the results, it can be found that atemperature rise characteristics equivalent to those in a conventionalcase can be kept by setting the adhered amount of antirust oil to anaverage film thickness of 10 μm or less.

(Verification of Residual Chloride Ion Amount)

After rolling bearings were fabricated by typical grinding process andall surfaces thereof were ground, chloride ions adhered thereon wereremoved to become below a detection limit of an analyzer.

After such pretreatment, chloride ions were newly adhered by treatmentsshown in Table 1, and then an amount of chloride ions was measured. Forthe measurement, after rolling bearings were immersed in a bath, inwhich a predetermined amount of ultrapure water was filled, during 2.5hours at a temperature of 80° C. so that chloride ions were dissolved, aliquid was collected from the bath and then an amount of chloride ionstherein were measured by a ion chromatography analyzer, DX-120, and aseparation column, IonPacAS 12A (4 mm), which are produced by DionexK.K. The measurement method was performed at conditions identical tothose of Explanation FIG. 6 of JIS K0127. Qualification was performedfor chloride ions, thereby calculating an amount per unit area. Theresults are shown in Table 1.

For rolling bearings, on which the same treatment was performed, arusting acceleration test was performed. In the rusting accelerationtest, after the antirust oil was applied to the rolling bearings at anaverage film thickness of 4.5 μm and the rolling bearings are left forthirty days in a high temperature and high humidity environment of 50°C., 90% RH, whether or not the surfaces of rolling bearings were rustedwas verified. The results are shown in Table 1.

TABLE 1 Amount of Samples Bearing surface treatment method chloride ionsRusting 1 Applying chloride ions by hand 13 ng/mm² Yes 2 Cleaning Sample1 to remove chloride  5 ng/mm² No ions 3 Applying artificial fingerprintliquid 25 ng/mm² Yes defined by JIS K 2246 4 Cleaning Sample 3 to removechloride 10 ng/mm² No ions

As shown in Table 1, rusting can be prevented when an amount of chlorideions is 5 ng/mm² to 10 ng/mm².

In addition, assuming that an amount of chloride ions contained in agrinding water is 0.1 mg/L, which is a minimum defined in the WaterworksLaw, it is believed that rolling bearings, which are typically groundand from which chloride ions does not removed, have chloride ions of fewtens to few hundreds ng/mm² adhered thereon, but when chloride ions arenot removed, rusting cannot be prevented if the antirust oil has a thinfilm thickness of less than 4.5 μm.

From this test, it can be found that, when an amount of chloride ions,which have been adhered on rolling bearings after removing chloride ionstherefrom, is set to 0.2 ng/mm² to 10 ng/mm², a favorable antirustperformance can be obtained by setting a film thickness of the antirustoil to 4.5 μm or more (4.5 μm to 10 μm) as defined in the preventinvention.

Although the present invention has been described with referenced to thedetailed and specific embodiments, it should be apparent to thoseskilled in the art that numerous changes and modifications can be madewithout departing the scope and spirit of the present invention.

This application is based on Japanese Patent Application No. 2013-115810filed on May 31, 2013, the entire content of which is incorporatedherein by reference.

INDUSTRIAL APPLICABILITY

The present invention is suitable for storing and transporting machinetool bearings (in particular, machine tool spindle bearings).

DESCRIPTION OF REFERENCE SIGNS

-   -   1 Angular ball bearing    -   2 Single-row cylindrical roller bearing    -   2A Inner ring    -   2B Cylindrical roller    -   2C Retainer    -   2D Outer ring    -   3 Double-row cylindrical roller bearing    -   3A Inner ring    -   3B Cylindrical roller    -   3C Retainer    -   3D Outer ring    -   10 Volatile corrosion inhibitor film    -   11 Sealing portion

What is claimed is:
 1. A rolling bearing comprising an inner ring, anouter ring, and a plurality of rolling elements retained between theinner ring and the outer ring by a retainer in a rollable manner,wherein antirust oil is provided to adhere, at an average film thicknessof 4.5 μm to 10 μm, to an entire surface of the bearing from whichchloride ions and sulfate ions are removed, and the bearing is put in abag made of a volatile corrosion inhibitor film.
 2. The rolling bearingaccording to claim 1, wherein an amount of residual chloride ionsadhered to the rolling bearing per unit area is 0.2 ng/mm² to 10 ng/mm².3. The rolling bearing according to claim 2, wherein the bearing is putin the bag in a state in which a bearing interior space defined by theinner ring, the outer ring and the rolling elements is charged withgrease.
 4. The rolling bearing according to claim 2, wherein the bearingis sealed by the bag.
 5. The rolling bearing according to claim 1,wherein the bearing is put in the bag in a state in which a bearinginterior space defined by the inner ring, the outer ring and the rollingelements is charged with grease.
 6. The rolling bearing according toclaim 1, wherein the bearing is sealed by the bag.
 7. A method ofpackaging a rolling bearing after assembling the rolling bearing frombearing components, the method comprising: after removing chloride ionsand sulfate ions from an entire surface of the bearing, providingantirust oil to adhere thereto at an average film thickness of 4.5 μm to10 μm, and putting the bearing in a bag made of a volatile corrosioninhibitor film.
 8. The method of packaging the rolling bearing accordingto claim 7, wherein the chloride ions and the sulfate ions are removedfrom the entire surface of the rolling bearing such that an amount ofresidual chloride ions adhered to the rolling bearing per unit area is0.2 ng/mm² to 10 ng/mm².
 9. The method of packaging the rolling bearingaccording to claim 8, wherein after the adhesion of the antirust oil, abearing interior space defined by an inner ring, an outer ring androlling elements is charged with grease.
 10. The method of packaging therolling bearing according to claim 8, wherein the bearing is sealed bythe bag.
 11. The method of packaging the rolling bearing according toclaim 7, wherein after the adhesion of the antirust oil, a bearinginterior space defined by an inner ring, an outer ring and rollingelements is charged with grease.
 12. The method of packaging the rollingbearing according to claim 7, wherein the bearing is sealed by the bag.